Azide compounds play a pivotal role for subsequent synthesis of organonitrogens such as amines and triazoles that are essential compounds in organic and materials chemistry. Triazoles that can be synthesized by the 'click' reaction have attracted attention in the development of pharmaceuticals and other industries. However, the azido groups are electrophilic and are susceptible to various nucleophiles such as carbanions. This poses a significant challenge for the synthesis of carbanions having azido groups.
